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Well, get someone to wrap an amp clamp over the alternator wire while it is running and squealing. Compare squealing and non-squealing amperage. If not belt alignment, then some strange full load, but for it to scream like that, even fully loaded it should not so that short of belt tension issues. Anyone local to you that is good with DSM's??? Or belts and alternators in general???
I have a few people that are good with DSM's but they are stumped. after the car stops squealing the RPM's raise about 500 RPMS. the only way to stop the squeal is to over tighten the belt. The last time i did that it warped the water pump arm that connects to the pulleys... i think the water pump pulley may be mis-aligned, and this 90 amp GVR4 alternator will not power the 400 watt amp and the sub barely works, big battery and relocation to trunk it is i guess